Off-spinner Sunny Gupta (4/67) and seamer Jaskaran Singh (3/52) shared the bulk of the spoils with India A regular Shahbaz Nadeem took 2 for 27 in 23 overs.
Opener Jiwanjot Singh struck double-century and Anmolpreet Singh hit a ton as Punjab reached 396 for two on the opening day of their Group D Ranji Trophy match against Goa on Tuesday.
Pacer Siraj grabbed 4 for 42 in 15 overs, whereas, India regular KL Rahul was castled by medium pacer Ravi Kiran for 4 runs.
Shaw and Shreyas Iyer, who has been picked in the India T20 team to face New Zealand, were in an aggressive frame of mind and attacked the Tamil Nadu bowlers.
The focus would be on Karnataka's stylish batsman K L Rahul and young paceman Mohammed Siraj of Hyderabad.
The 13-member squad primarily comprises of players from four states Hyderabad, Kerala, Madhya Pradesh and Punjab as these are the teams, which won't feature during the fifth round of the Ranji Trophy.
Rahul, who has been omitted from the New Zealand ODIs, would like to use the opportunity to make an impression after Karnataka made a solid start in the Ranji season.
Tamil Nadu now has four points from two matches and next take on Mumbai in Mumbai from October 24 in a crucial match in Group "C".
India's pace ace Mohammed Shami picked up eight wickets as Bengal walloped Chhattisgarh by an innings and 160 runs in a Ranji Trophy Group D encounter on Tuesday.
With seven points including a bonus by virtue of innings victory, Delhi are now on top of Group A with 10 points from two games.
Skipper Vinay Kumar, eyeing a comeback into the Indian squad, scalped six wickets in the match for Karnataka, four of them in the second innings.
Jadeja, after completing a double hundred on day two, took four wickets in the first innings while the remaining were picked up by another left-arm spinner, Dharmendersinh Jadeja.
In his fifth first-class season for Delhi, left-handed Manan scored 136 off 216 balls and then took 2 for 18 in 11 overs with his accurate left-arm orthodox spin taking a couple of wickets to put Delhi in driver's seat.
Jadeja made 201 runs off 313 balls with the help of 23 fours and two sixes, while Patel faced 167 balls for his 94 that was studded with 14 hits to the fence.
Ojha will not be able to play Hyderabad's Ranji opener versus Maharashtra at home tomorrow.
Additional weightage has also been given to Ranji Trophy with fringe India players told to be part of as many First- Class games as possible.
Bengal will also get the services of Test specialist Wriddhiman Saha and current India A left-hander Sudeep Chatterjee.
MS Dhoni was paid Rs 57,88,373 (Rs 57.88 lakh) as a share of gross revenue from the international tournaments held outside India.
Shami, who was part of the Indian ODI team has not been picked for the three-match T20 series, which opened the window for him to represent his stateside.
The squad also includes exciting young all-rounder Washington Sundar, who has impressed with his recent performances including in the Duleep Trophy final.
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