Puertas scored the 89th-minute equaliser for Granada with Barcelona hemmed in inside their box after Barca teenager Gavi Paez got his second booking with 10 minutes left.
Marco Asensio, Nacho Fernández, Vinícius Júnior and Ferland Mendy all scored to give Madrid its fourth straight straight victory in all competitions.
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In desperate move to find goal, Koeman sent in defender Gerard Pique to play as a striker in the closing minutes as the match ended 1-1.
It was the seventh consecutive winless opening match for Villarreal in the league, and it hasn't started the season with a win at home in six attempts.
Barcelona trailed 2-0 going into the 88th minute before Messi helped create goals for Antoine Griezmann and Jordi Alba as the Catalan club kept alive its chance of ending its title drought.
Messi slots an outrageous free-kick from underneath jumping Granada defenders despite a man guarding the wall to block such shot in Barcelona's 4-0 win; sending his son Mateo into jubilation.
Slots an outrageous free-kick from underneath jumping Granada defenders despite a man guarding the wall to block such shot in Barcelona's 4-0 win; Messi and Griezmann scores brace in the win.
After a tight first half, Casemiro evening opened the scoring with a 57th-minute header from Marco Asensio's cross and Karim Benzema sealed the win in the closing moments of the game.
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As many as 6 teams have the chance to go on top of the La Liga table this weekend.
Getafe registered a surprise win over Granada as the latter squandered chance to regain the top spot in the La Liga table.
Miseries continued for Barcelona as Ernesto Valverde's side conceded a 2-0 defeat to Granada, resulting in their worst league start in 25 years.
Joan Jordan scored the only goal of the game as Sevilla registered their second win of the La Liga.
Barcelona: FC Barcelona got a hat-trick from Lionel Messi and another goal from Neymar in a 4-0 victory here Saturday over Granada that put the Catalan football club back on top of the La Liga
Valencia, Spain: Two goals in each half gave Valencia a 4-0 win over relegation-threatened Granada in the Spanish league on Monday.Granada had managed to slow the host's pace in the first half until Javier Fuego
Barcelona, Spain: Cristiano Ronaldo erupted for his first five-goal game on Sunday, ending all talk of a dry spell as the Real Madrid star fueled a 9-1 demolition of Granada to keep the pressure on
Madrid: FC Barcelona forward Lionel Messi's foot is likely to be the main focus of interest as La Liga returns to action following the international break.The Argentine was unable to play in his country's two
Cordoba, Spain: Forward Nabil Ghilas scored before leaving injured to spark Cordoba's 2-0 win over visitors Granada on Monday in a meeting between two teams in the Spanish league's relegation zone.Ghilas used one touch to
BARCELONA, Spain: Cristiano Ronaldo extended his scoring streak to 12 straight games before setting up another goal to help Real Madrid ease to a 4-0 win at Granada and take the provisional lead of the
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