Kevin De Bruyne scored one and had a hand in two others, with Gabriel Jesus, Bernardo Silva and Sergio Aguero scoring along with an own-goal.
Hart spent 12 years at City and won two Premier League titles, but he dropped in the pecking order after Pep Guardiola's arrival and spent the last two seasons on loan to Torino and West Ham.
Burnley has picked up away points at three of last season's top-six teams, beating Chelsea on the opening day and drawing against Tottenham at Wembley.
Chelsea, which won 17 of its 19 home games last season, became the second straight team to begin its league title defence with a loss, after Leicester last season.
Liverpool, England: Burnley sank to the bottom of the Premier League after losing 1-0 at Everton on Saturday, with midfielder Ashley Barnes compounding the team's struggles by being sent off.Burnley was already trailing to Kevin
Burnley, England: Manchester City was stunned by relegation-threatened Burnley on Saturday, losing 1-0 in a further blow to its Premier League title defense.After losing two of its last three matches, City is five points behind
London: Chelsea was surprised by relegation-threatened Burnley on Saturday, conceding a late goal after Nemanja Matic was sent off in the 1-1 draw. Chelsea lead in the English Premier League was cut to five points.After
Manchester, England: Defender Chris Smalling scored twice after coming on as an early substitute to help Manchester United to a 3-1 win over Burnley that lifted the team to third place in the Premier League
Manchester, England: Manchester City threw away a 2-0 lead to draw 2-2 at home to struggling Burnley on Sunday, squandering the chance to close the gap on leader Chelsea to one point.David Silva and Fernandinho
Burnley, England: Raheem Sterling's second-half strike gave Liverpool its first league victory in four matches, beating Burnley 1-0 Friday despite turning in a poor performance at Turf Moor.Last year Liverpool was top of the Premier
Stoke, England: Burnley climbed off the bottom of the Premier League by beating Stoke 2-1 thanks to two first-half goals in the space of two minutes from striker Danny Ings on Saturday.Jonathan Walters' diving header
LONDON: A second-half double from Alexis Sanchez and a first goal for Calum Chambers handed Arsenal a 3-0 victory over Burnley on Saturday in the Premier League. Burnley frustrated Arsenal for much of the game but
BURNLEY, England: Diego Costa scored just 17 minutes into his debut and Cesc Fabregas had two assists in a superb performance as Chelsea opened its Premier League campaign with a 3-1 win at newcomer Burnley.
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