Langer resigned from his post on Saturday, unhappy with the short-term contract extension offered by Cricket Australia after a marathon seven-hour board meeting.
The announcement was made in a statement from Langer’s management company DSEG while Langer was flying from Melbourne to his hometown of Perth.
Langer, whose contract is due to end in June, guided Australia to its maiden T20 World Cup title last year and a dominant 4-0 Ashes victory recently.
At stumps, Australia's score read 12/2 with the hosts leading by 52 runs. Beth Mooney (7*) and Ellyse Perry (0*) are currently at the crease.
Starc has enjoyed a sensational year of international cricket and captured a combined 43 wickets at an average of 24.4 across all formats, 12 clear of the nation's next best.
Besides the hectic schedule, bubble life amid the COVID-19 pandemic has also taken a toll on cricketers, forcing them to switch off from the game.
As per a report in an Australian daily, the players are increasingly worrying about terrorist attacks in Pakistan.
The last time Pakistan had an ICC event on its soil was when it co-hosted the 1996 World Cup along with India and Sri Lanka.
After suffering a 1-2 series loss in South Africa, India dropped to the third spot while inaugural World Test Championship (WTC) winners New Zealand held onto their second position after a 1-1 drawn series at home against Bangladesh.
Langer was appointed head coach in the aftermath of the ball-tampering scandal in 2018 to overhaul the team's culture and regain the respect of the Australian public. His contract is due to end in June.
Australia won the first three matches in Brisbane, Adelaide and Melbourne to clinch the series and retain the Ashes before the teams played to a draw in Sydney.
Starc, who last played in the IPL in 2015, said he hasn't made the decision yet but entering his name for the league's mega auction, the nominations for which close on Friday, is "certainly on the table."
Statistically, the 31-year-old Starc is the finest pink-ball bowler in Test cricket, snaring 52 wickets at 18.23.
Hazlewood had suffered a side strain in the opening Test at the Gabba, Brisbane and hasn't featured in the series since.
Khawaja, playing Test cricket after more than two-and-a-half years, ground out a 260-ball 137 as Australia put up an imposing 416 for eight declared on Day 2 of the fourth Ashes Test at the Sydney Cricket Ground.
On a day marred with frequent rain interruptions, Smith was unbeaten on six and Khawaja was four not out when rain ended play for the day after Warner and Labuschagne perished following a good start.
Starc has done a turnaround from a below-average performance at the ICC T20 World Cup, and is now averaging more than 50 with the bat and less than 20 with the ball, which could earn him a batting order promotion at the SCG.
Khawaja is the only change announced by Australian Test skipper Pat Cummins after Head -- the hero of the first Test win at The Gabba -- tested COVID-19 positive after the conclusion of the Boxing Day Test.
Mitchell, now 55, alleged he was assaulted after a team doctor treated him with a sedative.
With Hazlewood on his way to peak fitness, Australia will have six in-form pace bowlers and one spinner to pick their squad and the selectors will have some "hard conversations" when they sit down to pick the squad. Skipper Pat Cummins, Mitchell Starc, Jhye Richardson, Scott Boland, and Michael Neser are the pacers on the selectors' list for the next Test.
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