In the second career meeting between the two players, Svitolina was in a strong position from the beginning as she took a 5-0 lead over Williams in the opening set and never returned.
Top-seeded Rafael Nadal lost to 18-year-old Denis Shapovalov 3-6, 6-4, 7-6 (4) in third round.
Roger Nadal breezed past Borna Coric of Croatia 6-1, 6-2 to advance to the third round, while Roger Federer routed Canadian Peter Polansky, 6-2, 6-1 in 53 minutes.
Eugenie Bouchard has now failed to make it past the second round in six straight tournaments.
The former World No.1 was also scheduled to play at the Rogers Cup in Toronto this week but withdrew because of injury.
Italian Sara Errani has blamed contamination from her mother's breast cancer medication.
The title was Zverev's first of his career on an outdoor hard court and gives him momentum heading into the U.S. Open, which starts Aug. 28.
The Indian qualifier, who savoured his best ever performance on the ATP World Tour, went down fighting 4-6 6-4 3-6 against the world number 45 from South Africa in the quarterfinals played last night.
AITA official said that the only reason Bopanna has not been nominated is because he has not been able to reach the criteria in 2016 to be eligible for the Arjuna Award.
Yuki Bhambri, ranked 200th in world rankings, recovered from a set down and registered what turned to be an emphatic 6-7, 6-3, 6-1 win over Guido Pella.
Bhambri will next face Argentina's Guido Pella in the round of 16 of ATP Citi Open.
Ecstatic to make a return in Montreal, Roger Federer said that 2017 season has been exciting so far and, therefore, he is looking forward to be back on the court.
Maria Sharapova, a wild-card entrant and five-time Grand Slam champion, won the opening four games of the match, lost the first three of the second set and cruised in the third.
The 30-year-old's comments came as she penned an emotional letter to his fans about her roller-coaster ride since making a return in April from her suspension for the use of Meldonium.
Djokovic has never missed a major tournament since he played his first major at the 2005 Australian Open. This is the third-longest active run among men and seventh-longest in history.
Under the supervision of India's former number one singles player Somdev a comprehensive plan has been submitted by the All India Tennis Association (AITA) to the Sports Ministry for approval.
The likes of Thombare, Kaur and Ankita Bhambri are ranked around 200-250 in the world and that is no mean achievement, the 30-year-old said.
The last time India hosted a WTA event - Royal Indian Open - was in 2012 in Pune when current world number five Elina Svitolina had won the singles title.
Vardhan and Matsui saved three of the four breakpoints they faced in the summit clash, which lasted one hour and 44 minutes. The win got Vardhan the biggest title triumph of his career.
Besides Clijsters and Roddick, four-time Paralympic wheelchair tennis medalist Monique Kalkman-van den Bosch of Dutch, tennis historian and journalist Steve Flink and late tennis instructor Vic Braden complete the full list.
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