North Korea
North Korea has always been belligerent and regularly uses its weapons as bargaining chips whenever they want something from other countries.
It was actually a signatory of the nuclear Non-Proliferation Treaty, or NPT, but they withdrew in 2003 after the United States cut off energy assistance because of North Korea's
suspected uranium enrichment program. It conducted its first test in 2006. While the Americans confirmed this, it is believed that it was not a complete success.