His family includes Sister Saraswati Karad. She is followed by elder brother Pandit Anna, who is actively involved in social and political work. He was third child in the family. He was followed by younger brothers, Manikrao and Venkatrao.
Munde has three daughters — Pankaja, Pritam and Yashashri. Pankaja is an MLA. Pritam is a doctor, and Yashashri is studying law.
He died in a car accident in New Delhi on 3rd June, 2014.